Not sure if this will apply to all of Spain, but it probably does,
One does not get the payment form from the polce any more, it must be downloaded from the internet at  Â
For those who do not speak Spanish,  this is my explanation of what the form means Click in the box you are selecting.
(If the form does not print, 3 copies plus an information sheet, check to see if you have missed an item marked with an  *)
Hope this helps.Â
If I have missed something please PM me.
THE FORM
±õ¶Ù·¡±·°Õ±õ¹ó±õ°ä´¡°ä±õÍѱ·                 Identification
N.I.F./N.I.E. (*)Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â leave blank if you are applying for an NIE (or do not have one)
Apellidos y nombre o razón social (*)   surname, followed by forenames
Domicilio                            details for your address (i.e. where you living / staying on the
                                    day you make the application)
Tipo de vÃa (*)                        Type of ‘road’ you live in Calle, Plaza etc
Nombre de la vÃa pública(*)            Street name
Núm. (*)                             Street number of your address
Esc                                 staircase number if appropriate
Piso                                floor level if appropriate
Teléfono                            telephone number, fixed or mobile
Municipio (*)Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Town in which you live
Provincia (*)Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Province
Código Postal (*)                     Post code
(*)                                  Item must be completed Â
(Heading) Tarjetas de identidad de extranjeros (TIE) y certificados de registro de residentes  comunitarios..
.Certificado de registro de residente comunitario o Tarjeta de residencia de familiar de un ciudadano de la Unión.       select for EU Citizen Reg application
(Heading)Â Documentos de identidad y tÃtulos y documentos de viaje a extranjeros indocumentados y otros documentos. Â Â Â
Asignación de Número de Identidad de Extranjero (NIE) a instancia del interesado.   Select for NIE application
    Â
Or choose an alternative reason as per lists.    Â
DECLARANTEÂ Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Person making application
Localidad (*)Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â The town in which you signed the form (that is a usual requirement on official papers)
Fecha (*)Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â The date of signing
INGRESOÂ Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â amount of PAYMENT
Importe euros
€                                  € 10.40  (if for an NIE)
Forma de pago (*)Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â Â how you will pay at the bank
En efectivo                         CashÂ
E.C. Adeudo en cuenta               Show account info If paying from your bank account